Palladium(II) Complexes of Monodentate Phosphine Ligands and Their Application as Catalyst in Suzuki-Miyaura C-C Coupling Reaction at Room Temperature
Citation
Yılmaz, M.K., Ince, S. (2018). Palladium(II) Complexes of Monodentate Phosphine Ligands and Their Application as Catalyst in Suzuki-Miyaura C-C Coupling Reaction at Room Temperature. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(2), 895-902. DOI: 10.18596/jotcsa.435122Abstract
A series of palladium(II) complexes from monodentate phosphine ligands (1a-4a) were successfully prepared and characterized with1H,31P,13C NMR, and HRMS techniques. These pre-catalysts were applied for the Suzuki-Miyaura C-C coupling reaction of phenylboronic acid with bromobenzene and the influence of the base and solvent on the performance of the pre-catalysts was investigated. Sterically hindered and electronically deactivated aryl bromides as well as activated ones gave the corresponding coupling products in good to excellent yields at room temperature. © 2018, Turkish Chemical Society. All rights reserved.