Perovskite SrCo1-xTixO3-d as anion-intercalated electrode materials for supercapacitors

Abstract

Perovskites oxides have recently been widely deployed in supercapacitors though they are suffering from poor electrochemical activity as electrode materials. Herein, a series of Ti-substituted perovskite SrCo1-xTixO3-delta (x = 0, 0.05, 0.10, 0.15, 0.20) are synthesized by solid-state reaction method for anion-intercalated supercapacitor electrode materials. The structural evolution, morphology and the electrochemical performance with the variation of Ti content are characterized in detail. The parent material SrCoO3-delta contains two phase: a hexagonal structure with space group R3:H (87.09 wt%) and a simple cubic structure with space group Pm((3) over bar)m (12.91 wt%). While a stable cubic structure with Pm((3) over bar)m space group is obtained after Ti substitution and the electrochemical performance is also significantly optimized. A highest specific capacitance (Cs) of 625.0 F g(-1) at 1 A g(-1) is achieved in SrCo0.9Ti0.1O3-delta sample. The superior electrochemical performance of SrCo0.9Ti0.1O3-delta is attributed to the stable cubic structure with higher conductivity and large amount of oxygen vacancy which directly contributes to the anion-intercalated energy storage. In addition, the asymmetric supercapacitor combined with activated carbon electrode exhibits a high specific capacitance of 114.4 F g(-1) (50.8 mAh g(-1)) and 98.3 F g(-1) (42.7 mAh g-1) at 5 mV s(-1) and 1 A g(-1), respectively. The device presents an energy density of 69.9 Wh kg(-1) at power density of 1600 W kg(-1) with a working voltage of 1.6 V.