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Photoredox cross-coupling: Ir/NidDual catalysis for the synthesis of Benzylic Ethers
(AMER CHEMICAL SOC., 2015)
Single-electron transmetalation has emerged as an enabling paradigm for the cross-coupling of C-sp(3) hybridized organotrifluoroborates. Cross-coupling of alpha-alkoxymethyl-trifluoroborates with aryl and heteroaryl bromides ...
Single-electron transmetalation: An enabling technology for secondary alkylboron cross-coupling
(AMER CHEMICAL SOC, 2015)
Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates ...