Pd(II) complexes of Schiff bases and their application as catalysts in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions

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dc.authoridKeles, Mustafa/0000-0003-2669-1818
dc.authoridKeles, Hulya/0000-0002-2450-7290;
dc.contributor.authorKeles, Mustafa
dc.contributor.authorKeles, Hulya
dc.contributor.authorEmir, Duygu Melis
dc.date.accessioned2025-08-12T08:28:47Z
dc.date.issued2015
dc.departmentOsmaniye Korkut Ata Üniversitesi
dc.description.abstractSchiff bases of 2-(phenylthio)aniline, (C6H5)SC6H4NCR (R=(o-CH3)(C6H5), (o-OCH3)(C6H5) or (o-CF3)(C6H5)), and their palladium complexes (PdLCl2) were synthesized. The compounds were characterized using H-1 NMR and C-13 NMR spectroscopy and micro analysis. Also, electrochemical properties of the ligands and Pd(II) complexes were investigated in dimethylformamide-LiClO4 solution with cyclic and square wave voltammetry techniques. The Pd(II) complexes showed both reversible and quasi-reversible processes in the -1.5 to 0.3V potential range. The synthesized Pd(II) complexes were evaluated as catalysts in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions. Copyright (c) 2015 John Wiley & Sons, Ltd.
dc.description.sponsorshipOsmaniye Korkut Ata University; Scientific and Technological Research Council of Turkey [113Z497]
dc.description.sponsorshipThe authors thank Osmaniye Korkut Ata University for financial support and the Scientific and Technological Research Council of Turkey (project no. 113Z497) for a grant. The authors also thank Kirsi Ekroos for technical support.
dc.identifier.doi10.1002/aoc.3329
dc.identifier.endpage548
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue8
dc.identifier.scopus2-s2.0-84937966587
dc.identifier.scopusqualityQ1
dc.identifier.startpage543
dc.identifier.urihttps://doi.org/10.1002/aoc.3329
dc.identifier.urihttps://hdl.handle.net/20.500.12502/5636
dc.identifier.volume29
dc.identifier.wosWOS:000358533300009
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250812
dc.subjectSchiff base
dc.subjectpalladium
dc.subjectMizoroki-Heck coupling
dc.subjectSuzuki-Miyaura coupling
dc.subjectelectrochemistry
dc.titlePd(II) complexes of Schiff bases and their application as catalysts in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions
dc.typeArticle

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