Pincer Type Ditertiary Aminomethylphosphine-Pd(II) Complexes Supported on Multi-Walled Carbon Nanotube: Catalytic Properties in Heck C-C Coupling Reactions

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dc.authoridKeles, Mustafa/0000-0003-2669-1818
dc.contributor.authorUrus, Serhan
dc.contributor.authorAdiguzel, Hamza
dc.contributor.authorKeles, Mustafa
dc.contributor.authorKarteri, Ibrahim
dc.date.accessioned2025-08-12T08:28:24Z
dc.date.issued2017
dc.departmentOsmaniye Korkut Ata Üniversitesi
dc.description.abstractPincer type aminomethylphosphine-Pd(II) complexes supported on multi-walled carbon nanotube (MWCNT) have been synthesized and characterized using X-Ray diffraction spectrometry, scanning electron microscopy, thermal analysis, energy dispersive X-Ray, Fourier transform infrared spectrometry, transmission electron microscopy (TEM) and ultraviolet-visible spectrometry techniques. The novel complexes were tried as catalysts in Heck C-C coupling reactions. The crystallite size and lattice strain of the MWCNT based compounds were calculated by the Scherrer's equation. The optical parameters of the MWCNT based structures were analyzed and the band gap enhanced from 4.42 to 4.98 eV. Different solvents (toluene, 1,4-diooxane, DMF and NMP) and bases (Et3N, -Na2CO3, NaOAc and K2CO3) were tried at different temperatures (80, 100 and 110 degrees C) in the cross-coupling of bromobenzene with styrene. The optimum yield was found in the presence of K2CO3, 110 degrees C in 1,4-dioxane solvent system.
dc.description.sponsorshipScientific & Technological Research Council of Turkey (TUBITAK) [111T211]; Kahramanmaras Sutcu Imam University [2013/6-33M]
dc.description.sponsorshipWe would like to thank The Scientific & Technological Research Council of Turkey (TUBITAK) (Project No.: 111T211) and Kahramanmaras Sutcu Imam University (Project No.: 2013/6-33M) for their financial supports.
dc.identifier.doi10.1007/s10904-017-0642-5
dc.identifier.endpageS145
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.scopus2-s2.0-85027716976
dc.identifier.scopusqualityQ1
dc.identifier.startpageS138
dc.identifier.urihttps://doi.org/10.1007/s10904-017-0642-5
dc.identifier.urihttps://hdl.handle.net/20.500.12502/5429
dc.identifier.volume27
dc.identifier.wosWOS:000423903600016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250812
dc.subjectPhosphine
dc.subjectCarbon nanotube
dc.subjectCatalyst
dc.subjectHeck coupling
dc.subjectOptical property
dc.titlePincer Type Ditertiary Aminomethylphosphine-Pd(II) Complexes Supported on Multi-Walled Carbon Nanotube: Catalytic Properties in Heck C-C Coupling Reactions
dc.typeArticle

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