Iminophosphine palladium(II) complexes: synthesis, characterization, and application in Heck cross-coupling reaction of aryl bromides

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dc.authoridGuzel, Bilgehan/0000-0002-0234-6940
dc.authoridYilmaz, Mustafa Kemal/0000-0002-9969-3956;
dc.contributor.authorYılmaz, Mustafa Kemal
dc.contributor.authorGuzel, Bilgehan
dc.date.accessioned2025-08-12T08:28:47Z
dc.date.issued2014
dc.departmentOsmaniye Korkut Ata Üniversitesi
dc.description.abstractPalladium(II) complexes containing phosphorus and nitrogen donor atoms (iminophosphine), dichlorido{N-[2-(diphenylphosphino)benzylidene]-2-trifluoromethylaniline}palladium(II) 1, dichlorido{N-[2-(diphenylphosphino)benzylidene]-3-trifluoromethylaniline}palladium(II) 2, dichlorido{N-[2-(diphenylphosphino)benzylidene]-2-methylaniline}palladium(II) 3, dichlorido{N-[2-(diphenylphosphino)benzylidene]-3-methylaniline}palladium(II) 4 have been successfully synthesized and fully characterized by FT-IR and NMR (1H, 31P, 19F, and 13C) spectroscopy techniques. These complexes were first step tested in the reaction of bromobenzene and styrene to determine the optimal coupling reaction conditions and then successfully applied as catalysts for Heck cross-coupling reactions of activated and deactivated aryl bromides with styrene derivatives and several acrylates. Copyright (c) 2014 John Wiley & Sons, Ltd.
dc.description.sponsorshipCukurova University Scientific Research Projects [FEF2011D9]; Associate Professor Mustafa KELES
dc.description.sponsorshipThe authors are grateful to the Cukurova University Scientific Research Projects (FEF2011D9) and Associate Professor Mustafa KELES for providing financial support for this research.
dc.identifier.doi10.1002/aoc.3158
dc.identifier.endpage536
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue7
dc.identifier.scopus2-s2.0-84902543852
dc.identifier.scopusqualityQ1
dc.identifier.startpage529
dc.identifier.urihttps://doi.org/10.1002/aoc.3158
dc.identifier.urihttps://hdl.handle.net/20.500.12502/5639
dc.identifier.volume28
dc.identifier.wosWOS:000337614700009
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250812
dc.subjectiminophosphine
dc.subjectpalladium
dc.subjectHeck cross-coupling reaction
dc.subjectaryl bromides
dc.titleIminophosphine palladium(II) complexes: synthesis, characterization, and application in Heck cross-coupling reaction of aryl bromides
dc.typeArticle

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